Most musical notes are sounds that have a particular pitch. The pitch depends on the main frequency of the sound; the higher the frequency, and shorter the wavelength, of the sound waves, the higher the pitch is. But musical sounds don't have just one frequency. Sounds that have only one frequency are not very interesting or pretty. They are about as musical and expressive as the beeping of a watch alarm or the hum of a refrigerator. On the other hand, sounds that have too many frequencies, like the sound of glass breaking or of ocean waves crashing on a beach, may be interesting and even pleasant. But they don't have a particular pitch, so they usually aren't considered musical notes.
When someone plays or sings a note, only a very particular set of frequencies is heard. Imagine that each note that comes out of the instrument is a smooth mixture of many different pitches. These different pitches are called harmonics, and they are blended together so well that you do not hear them as separate notes at all. Instead, the harmonics give the note its color.
What is the color of a sound? Say an oboe plays a middle C. Then a flute plays the same note at the same loudness as the oboe. It is still easy to tell the two notes apart, because an oboe sounds different from a flute. This difference in the sounds is the color, or timbre (pronounced "TAM-ber") of the notes. Like a color you see, the color of a sound can be bright and bold or deep and rich. It can be heavy, light, murky, thin, or transparently clear. Some other words that musicians use to describe the timbre of a sound are: reedy, brassy, piercing, mellow, thin, hollow, focussed, breathy (pronounced BRETH-ee) or full.
Listen to recordings of different instruments playing alone or playing very prominently above a group. Some suggestions: an unaccompanied violin or cello sonata, a flute, oboe, trumpet, or horn concerto, native American flute music, classical guitar, bagpipes, steel pan drums, panpipes, or organ. For each instrument, what "color" words would you use to describe the timbre of each instrument? Use as many words as you can that seem appropriate, and try to think of some that aren't listed above. Do any of the instruments actually make you think of specific shades of color, like fire-engine red or sky blue?
Although trained musicians will generally agree that a particular sound is reedy, thin, or full, there are not any hard-and-fast right-and-wrong answers to this exercise.
Where do the harmonics, and the timbre, come from? When a string vibrates, the main pitch you hear is from the vibration of the whole string back and forth. That is the fundamental, or first harmonic. But the string also vibrates in halves, in thirds, fourths, and so on. Each of these fractions also produces a harmonic. The string vibrating in halves produces the second harmonic; vibrating in thirds produces the third harmonic, and so on.
This method of naming and numbering harmonics is the most straightforward and least confusing, but there are other ways of naming and numbering harmonics, and this can cause confusion. Some musicians do not consider the fundamental to be a harmonic; it is just the fundamental. In that case, the string halves will give the first harmonic, the string thirds will give the second harmonic and so on. When the fundamental in calculations, it is called the first partial, and the rest of the harmonics are the second, third, fourth partials and so on. Also, some musicians use the term overtones as a synonym for harmonics. For others, however, an overtone is any frequency (not necessarily a harmonic) that can be heard resonating with the fundamental. The sound of a gong or cymbals will include overtones that aren't harmonics; that's why the gong's sound doesn't seem to have as definite a pitch as the vibrating string does. If you are uncertain what someone means by the second harmonic or by the term overtones, ask for clarification.
A column of air vibrating inside a tube is different from a vibrating string, but the column of air can also vibrate in halves, thirds, fourths, and so on, of the fundamental, so the harmonic series will be the same. So why do different instruments have different timbres? The difference is the relative loudness of all the different harmonics compared to each other. When a clarinet plays a note, perhaps you can only hear the odd-numbered harmonics; when a French horn plays the same notes, perhaps the fifth and tenth harmonics are the strongest. This is what you hear that allows you to recognize that it is a clarinet or horn that is playing.