Summary: Using CNF and DNF with first-order-logic.
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In first-order logic, normal forms are still useful for providing a notion of a canonical form. However, their other benefit of corresponding closely to truth tables does not apply here, since truth tables aren't useful for first-order logic.
A formula in Prenex Conjunctive Normal Form, or Prenex CNF, has a body in CNF preceded by a series of quantifiers. Similarly, a formula in Prenex Disjunctive Normal Form, or Prenex DNF, has a body in DNF preceded by a series of quantifiers.
Assuming
Every formula has an equivalent prenex CNF formula and equivalent prenex CNF formula. For brevity, we'll skip proving this.