We have ruled out the first two mechanisms (i.e., changes in albedo and insolation) as reasons for the recent increase in global temperatures. But when we look at panel (c) in Figure Radiative Forcings & Simulated Temperatures, we notice that the “all other forcing” curves point to a rapid increase in the amount of energy retained by the earth-atmosphere system over the last 200 years. What is responsible for the increasing tail on this graph? Have humans altered the composition of the Earth’s atmosphere to make it more efficient at absorbing the infrared radiation that would have otherwise been lost to space? Is there proof of a human enhancement to the natural greenhouse effect? Can we explain the recent warming on an anthropogenic adjustment to the greenhouse gases like carbon dioxide (CO2)? Is an “enhanced greenhouse effect” to blame for the fact that the top ten warmest years since the modern era of instrument measurements have occurred since 1995, as seen in Figure Annual Global Temperature Anomalies.
Long before the term “global warming” became a common household phrase, nineteenth-century Irish physicist John Tyndall said, “Remove for a single summer-night the aqueous vapor from the air which overspreads this country, and you would assuredly destroy every plant capable of being destroyed by a freezing temperature.” This now famous quote reveals the importance of greenhouse gases, like water vapor, in maintaining a balance between the incident solar radiation and the emitted terrestrial radiation. Tyndall understood that without greenhouse gases, water vapor being the most abundant, the earth’s temperature would be markedly cooler. The global average surface temperature is approximately 15°C (59°F) but if the greenhouse gases were removed, the average global temperature would plummet to -18°C (0°F). Remember that these gases make up a small fraction of the composition of the atmosphere! Therefore, adjustments to their concentration will produce dramatic effects.
To understand why these gases are so efficient at keeping the planet warm, let’s examine Figure Atmospheric Transmission. The top panel of this figure shows the normalized intensity of the radiation emitted by both the sun and earth as a function of wavelength. The middle panel shows the total atmospheric absorption spectrum and the bottom panel shows the individual gas absorption spectrum (excluding Nitrogen and Argon). Notice from the top panel that the sun’s peak energy emission falls within the visible portion of the spectrum and suffers very little atmospheric absorption (middle panel). The peak emission wavelength for the earth is in the thermal infrared (IR), and it is effectively absorbed by water vapor (H20), carbon dioxide (CO2), methane (CH4) and nitrous oxide (N02). The primary purpose of this figure is to show that the gases in the earth’s atmosphere are transparent to the sun’s peak energy emission (visible light) but not the earth’s peak emission (thermal IR). It is through the absorption of the earth’s outgoing thermal infrared radiation that the global average temperature warms approximately 60°F over what it would be without greenhouse gases.
Are humans altering the natural greenhouse effect? Based upon our assessment so far, this is the final mechanism by which the global climate can be changed. Let’s look into the alteration of the chemistry and composition of the earth’s atmosphere. First are humans increasing the amount of water vapor, the most abundant but also weakest greenhouse gas in the atmosphere? As the air temperature increases, the amount of water vapor the atmosphere can hold also increases. However, a closer investigation of the water cycle is needed to understand what will happen to this increase in water vapor. In this cycle, the amount of evaporation must equal the amount of condensation and thus precipitation on a global scale. This equilibrium must be achieved or else water would end up entirely in its liquid form or in its vapor form. Also due to the speed at which the hydrological cycle operates, a large increase in water vapor would be quickly precipitated out of the atmosphere.
Other greenhouse gases progress through their respective cycles much more slowly than water. There are vast amounts of carbon and carbon dioxide in the earth-atmosphere system. Most carbon is locked up in rocks, where it may remain for millions of years. The carbon dioxide that is mobile, however, is mostly found in other places: the ocean, soils, vegetation, fossil fuels like coal, oil, and natural gas, and also in small concentrations in the atmosphere. These reservoirs of CO2 can exchange mass like oceans and clouds do in the water cycle, but with one extremely important difference–the exchange rate is much slower. That means the system can get out of balance and remain out of balance for a long time, hundreds or thousands of years. There are two primary mechanisms for sequestering carbon dioxide that is released into the atmosphere: it can be captured by the respiration of plants, or dissolved in the ocean.
However, the rate at which plants and oceans can take CO2 out of the atmosphere is fixed. Therefore, if a surplus of CO2 is added to the atmosphere, it will stay there for a long time. This has major implications, given the fact that CO2 is a powerful greenhouse gas. The question then to ask becomes, “is this exchange rate out of balance?”
The current average concentration of CO2 in the atmosphere is about 390 parts per million (PPM), which means there are 390 parts of CO2 per million parts of air. That does not seem like very much, but if that small amount of carbon dioxide were removed from the air, the global average temperature would plummet. Has this concentration been changing? To answer the question, we will turn to the findings of Richard Keeling, whose life’s work was the observation of CO2 concentrations at the Mauna Loa Observatory in Hawaii. Beginning in the early 1950s, observations of CO2, a well-mixed gas in our atmosphere, have shown a remarkable climb in concentration. (see Figure CO2 Concentrations at the Mauna Loa Observatory) The “Keeling Curve,” as it is sometimes called, clearly shows that since the 1950s CO2 concentrations have increased steadily from 315 ppm to 390 ppm. The zigzag nature of this graph is due to life cycle of plants in the NH. The NH has much more land area that the SH, so when spring and summer arrive in the NH, the abundance of new plant life reduces the CO2 concentrations in the atmosphere. When the plants die or become dormant in the fall and winter, CO2 concentrations spike again.
What is troublesome about this figure is that the carbon cycle is out of its normal rhythm and a surplus of CO2, a known greenhouse gas, is building in the earth’s atmosphere. Where is this surplus coming from? To answer this question, let’s look at two historical records of CO2 concentrations taken from ice core deposits. The top panel in Figure Changes in Greenhouse Gases from Ice Core and Modern Data shows the past 10,000 years of atmospheric CO2 concentrations. Before 1750, the amount of CO2 in the atmosphere was relatively steady at 280 ppm. Since 1750 there has been a dramatic increase in CO2 concentrations.
If we look even further back in time, over the last half million years, we see a similar story. (see Figure Evidence of Climate Change) The current concentration of CO2 in the earth’s atmosphere is higher than at any time in the past half million years. Where is this abundance of CO2 coming from? Which reservoirs are being depleted of their CO2 while the atmosphere takes on more? The answer lies in the burning of fossil fuels and in the deforestation of significant chunks of the earth’s forest biomes. Notice the spike in CO2 concentrations beginning around 1750. This time period marks the beginning of the industrial revolution, when fossil fuels overtook wood as the primary energy source on our planet. Over the subsequent two and a half centuries, oil, coal, and natural gas have been extracted from their underground reservoirs and burned to generate electricity and power modern forms of transportation. The exhaust from this process is currently adding 30 billions of tons, or gigatons (Gt), of carbon dioxide to the atmosphere each year. Combine this addition of CO2, a known greenhouse gas, to the subtraction of one of the sinks of CO2 through deforestation and the imbalance grows even further.
What is the end result? By examining the earth’s climate, both current and past and by investigating the three ways in which climate can change, we have arrived at the conclusion that the current warming is being caused by an imbalance in the carbon cycle that has been induced by human activity, namely the burning of fossil fuels. The record warmth over the last 1,300 years is very likely to have been caused by human decisions that have lead to a change in the chemistry of the atmosphere, and which has altered the natural climate variability toward warmer global temperatures. We are essentially changing the climate faster and in a different direction than natural processes have intended.
"An interesting piece to start conversations about sustainability. "